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Nitrogen Arylation for Macrocyclization of Unprotected Peptides

We describe an efficient and mild method for the synthesis of macrocyclic peptides via nitrogen arylation from unprotected precursors. Various electro-philes and lysine-based nucleophiles were investigated and showed high-yielding product formation, even for a macrocyclization scan with 14 variants....

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lautrette, Guillaume, Touti, Fayçal, Lee, Hong Geun, Dai, Peng, Pentelute, Bradley L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6150454/
https://ncbi.nlm.nih.gov/pubmed/27332147
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b03757
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