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Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy
The metabolism of many anaerobes relies on [NiFe]-hydrogenases, whose characterization when bound to substrates has proven non-trivial. Presented here is direct evidence for a hydride bridge in the active site of the (57)Fe-labelled fully reduced Ni-R form of Desulfovibrio vulgaris Miyazaki F [NiFe]...
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| Pubblicato in: | Nat Commun |
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| Autori principali: | , , , , , , , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Nature Publishing Group
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4531378/ https://ncbi.nlm.nih.gov/pubmed/26259066 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8890 |
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