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A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel–iron–hydride in [NiFe] hydrogenase

Direct spectroscopic evidence for a hydride bridge in the Ni–R form of [NiFe] hydrogenase has been obtained using iron-specific nuclear resonance vibrational spectroscopy (NRVS). The Ni–H–Fe wag mode at 675 cm(−1) is the first spectroscopic evidence for a bridging hydride in Ni–R as well as the firs...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Veröffentlicht in:J Synchrotron Radiat
Hauptverfasser: Wang, Hongxin, Yoda, Yoshitaka, Ogata, Hideaki, Tanaka, Yoshihito, Lubitz, Wolfgang
Format: Artigo
Sprache:Inglês
Veröffentlicht: International Union of Crystallography 2015
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4629863/
https://ncbi.nlm.nih.gov/pubmed/26524296
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600577515017816
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