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A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel–iron–hydride in [NiFe] hydrogenase
Direct spectroscopic evidence for a hydride bridge in the Ni–R form of [NiFe] hydrogenase has been obtained using iron-specific nuclear resonance vibrational spectroscopy (NRVS). The Ni–H–Fe wag mode at 675 cm(−1) is the first spectroscopic evidence for a bridging hydride in Ni–R as well as the firs...
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| Publicat a: | J Synchrotron Radiat |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
International Union of Crystallography
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4629863/ https://ncbi.nlm.nih.gov/pubmed/26524296 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600577515017816 |
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