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Branched/linear selectivity in palladium-catalyzed allyl-allyl cross-couplings: The role of ligands

While Pd-catalyzed allyl-allyl cross-couplings in the presence of small-bite-angle bidentate ligands reliably furnish the branched regioisomer with high levels of selectivity, cross-couplings in the presence of large-bite-angle bidentate ligands give varying, often unpredictable, levels of selectivi...

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Publicado en:Tetrahedron
Autores principales: Ardolino, Michael J., Morken, James P.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2015
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4531376/
https://ncbi.nlm.nih.gov/pubmed/26279591
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.05.015
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