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Diastereocontrol in Asymmetric Allyl-Allyl Cross-Coupling: Stereocontrolled Reaction of Prochiral Allylboronates with Prochiral Allyl Chlorides

The palladium catalyzed allyl-allyl cross-coupling was investigated with substituted prochiral allylic boronates. These reactions deliver products bearing adjacent stereocenters and the issue of diastereocontrol is therefore paramount. Under appropriately modified conditions, this allyl-allyl coupli...

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Bibliografske podrobnosti
Main Authors: Brozek, Laura A., Ardolino, Michael J., Morken, James P.
Format: Artigo
Jezik:Inglês
Izdano: 2011
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3219057/
https://ncbi.nlm.nih.gov/pubmed/21973180
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2075967
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