Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications**

Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI) CH(2)OO and CH(3)CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and acetic acid (CH(3)COOH), employing two complementary techniques: multiplexed photoionization mass spectrometry and cavit...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Welz, Oliver, Eskola, Arkke J, Sheps, Leonid, Rotavera, Brandon, Savee, John D, Scheer, Adam M, Osborn, David L, Lowe, Douglas, Murray Booth, A, Xiao, Ping, Anwar H Khan, M, Percival, Carl J, Shallcross, Dudley E, Taatjes, Craig A
Materialtyp: Artigo
Språk:Inglês
Publicerad: WILEY-VCH Verlag 2014
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4499262/
https://ncbi.nlm.nih.gov/pubmed/24668781
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201400964
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