Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate

Isoprene has the highest emission into Earth’s atmosphere of any nonmethane hydrocarbon. Atmospheric processing of alkenes, including isoprene, via ozonolysis leads to the formation of zwitterionic reactive intermediates, known as Criegee intermediates (CIs). Direct studies have revealed that reacti...

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Udgivet i:Proc Natl Acad Sci U S A
Main Authors: Caravan, Rebecca L., Vansco, Michael F., Au, Kendrew, Khan, M. Anwar H., Li, Yu-Lin, Winiberg, Frank A. F., Zuraski, Kristen, Lin, Yen-Hsiu, Chao, Wen, Trongsiriwat, Nisalak, Walsh, Patrick J., Osborn, David L., Percival, Carl J., Lin, Jim Jr-Min, Shallcross, Dudley E., Sheps, Leonid, Klippenstein, Stephen J., Taatjes, Craig A., Lester, Marsha I.
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2020
Fag:
Physical Sciences
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7211945/
https://ncbi.nlm.nih.gov/pubmed/32321826
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1916711117
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