Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications**

Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI) CH(2)OO and CH(3)CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and acetic acid (CH(3)COOH), employing two complementary techniques: multiplexed photoionization mass spectrometry and cavit...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Welz, Oliver, Eskola, Arkke J, Sheps, Leonid, Rotavera, Brandon, Savee, John D, Scheer, Adam M, Osborn, David L, Lowe, Douglas, Murray Booth, A, Xiao, Ping, Anwar H Khan, M, Percival, Carl J, Shallcross, Dudley E, Taatjes, Craig A
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2014
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4499262/
https://ncbi.nlm.nih.gov/pubmed/24668781
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201400964
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