Functionalized Hydroperoxide Formation from the Reaction of Methacrolein-Oxide, an Isoprene-Derived Criegee Intermediate, with Formic Acid: Experiment and Theory

Methacrolein oxide (MACR-oxide) is a four-carbon, resonance-stabilized Criegee intermediate produced from isoprene ozonolysis, yet its reactivity is not well understood. This study identifies the functionalized hydroperoxide species, 1-hydroperoxy-2-methylallyl formate (HPMAF), generated from the re...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Vansco, Michael F., Zuraski, Kristen, Winiberg, Frank A. F., Au, Kendrew, Trongsiriwat, Nisalak, Walsh, Patrick J., Osborn, David L., Percival, Carl J., Klippenstein, Stephen J., Taatjes, Craig A., Lester, Marsha I., Caravan, Rebecca L.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2021
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8161369/
https://ncbi.nlm.nih.gov/pubmed/34065491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26103058
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