Functionalized Hydroperoxide Formation from the Reaction of Methacrolein-Oxide, an Isoprene-Derived Criegee Intermediate, with Formic Acid: Experiment and Theory

Methacrolein oxide (MACR-oxide) is a four-carbon, resonance-stabilized Criegee intermediate produced from isoprene ozonolysis, yet its reactivity is not well understood. This study identifies the functionalized hydroperoxide species, 1-hydroperoxy-2-methylallyl formate (HPMAF), generated from the re...

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Bibliografiset tiedot
Julkaisussa:Molecules
Päätekijät: Vansco, Michael F., Zuraski, Kristen, Winiberg, Frank A. F., Au, Kendrew, Trongsiriwat, Nisalak, Walsh, Patrick J., Osborn, David L., Percival, Carl J., Klippenstein, Stephen J., Taatjes, Craig A., Lester, Marsha I., Caravan, Rebecca L.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: MDPI 2021
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Article
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC8161369/
https://ncbi.nlm.nih.gov/pubmed/34065491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26103058
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