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Functionalized Hydroperoxide Formation from the Reaction of Methacrolein-Oxide, an Isoprene-Derived Criegee Intermediate, with Formic Acid: Experiment and Theory

Methacrolein oxide (MACR-oxide) is a four-carbon, resonance-stabilized Criegee intermediate produced from isoprene ozonolysis, yet its reactivity is not well understood. This study identifies the functionalized hydroperoxide species, 1-hydroperoxy-2-methylallyl formate (HPMAF), generated from the re...

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Bibliografske podrobnosti
izdano v:Molecules
Main Authors: Vansco, Michael F., Zuraski, Kristen, Winiberg, Frank A. F., Au, Kendrew, Trongsiriwat, Nisalak, Walsh, Patrick J., Osborn, David L., Percival, Carl J., Klippenstein, Stephen J., Taatjes, Craig A., Lester, Marsha I., Caravan, Rebecca L.
Format: Artigo
Jezik:Inglês
Izdano: MDPI 2021
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC8161369/
https://ncbi.nlm.nih.gov/pubmed/34065491
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules26103058
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