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Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates

The rate coefficients for gas‐phase reaction of trifluoroacetic acid (TFA) with two Criegee intermediates, formaldehyde oxide and acetone oxide, decrease with increasing temperature in the range 240–340 K. The rate coefficients k(CH(2)OO + CF(3)COOH)=(3.4±0.3)×10(−10) cm(3) s(−1) and k((CH(3))(2)COO...

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書誌詳細
出版年:Angew Chem Int Ed Engl
主要な著者: Chhantyal‐Pun, Rabi, McGillen, Max R., Beames, Joseph M., Khan, M. Anwar H., Percival, Carl J., Shallcross, Dudley E., Orr‐Ewing, Andrew J.
フォーマット: Artigo
言語:Inglês
出版事項: John Wiley and Sons Inc. 2017
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5575497/
https://ncbi.nlm.nih.gov/pubmed/28614628
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703700
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