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Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates
The rate coefficients for gas‐phase reaction of trifluoroacetic acid (TFA) with two Criegee intermediates, formaldehyde oxide and acetone oxide, decrease with increasing temperature in the range 240–340 K. The rate coefficients k(CH(2)OO + CF(3)COOH)=(3.4±0.3)×10(−10) cm(3) s(−1) and k((CH(3))(2)COO...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
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| Hoofdauteurs: | , , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2017
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5575497/ https://ncbi.nlm.nih.gov/pubmed/28614628 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201703700 |
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