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Cu-catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration

[Image: see text] A Cu(I)-catalyzed 1,3-halogen migration reaction effectively recycles an activating group by transferring bromine or iodine from a sp(2) to a benzylic carbon with concomitant borylation of the Ar-X bond. The resulting benzyl halide can be reacted in the same vessel under a variety...

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Publicat a:J Am Chem Soc
Autors principals: Grigg, R. David, Van Hoveln, Ryan, Schomaker, Jennifer M.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4490833/
https://ncbi.nlm.nih.gov/pubmed/22985198
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja306446m
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