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Cu-catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration
[Image: see text] A Cu(I)-catalyzed 1,3-halogen migration reaction effectively recycles an activating group by transferring bromine or iodine from a sp(2) to a benzylic carbon with concomitant borylation of the Ar-X bond. The resulting benzyl halide can be reacted in the same vessel under a variety...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4490833/ https://ncbi.nlm.nih.gov/pubmed/22985198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja306446m |
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