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Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration

An ongoing challenge in modern catalysis is to identify and understand new modes of reactivity promoted by earth-abundant and inexpensive first-row transition metals. Herein, we report a mechanistic study of an unusual copper(I)-catalyzed 1,3-migration of 2-bromostyrenes that reincorporates the brom...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Van Hoveln, Ryan, Hudson, Brandi M., Wedler, Henry B., Bates, Desiree M., Le Gros, Gabriel, Tantillo, Dean J., Schomaker, Jennifer M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4701576/
https://ncbi.nlm.nih.gov/pubmed/25828031
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja511236d
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