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Stereocontrolled 1,3-Phosphatyloxy and 1,3-Halogen Migration Relay Toward Highly Functionalized 1,3-Dienes
A double migratory cascade reaction of α-halogen-substituted propargylic phosphates to produce highly functionalized 1,3-dienes has been developed. This transformation features 1,3-phosphatyloxy group migration followed by 1,3-shifts of bromine and chlorine, as well as unprecedented 1,3-migration of...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3376387/ https://ncbi.nlm.nih.gov/pubmed/22489740 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja301243t |
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