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Beyond Benzyl Grignards: Facile Generation of Benzyl Carbanions from Styrenes
[Image: see text] The facile generation of benzyl anion equivalents from styrenes has been achieved. A Cu-catalyzed hydroboration is used in conjunction with sterically-induced cleavage of the C-B bond with tBuOK. Quenching this reactive intermediate with heterocumulene electrophiles, including CO(2...
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| Publicado en: | Chemistry |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2012
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4490829/ https://ncbi.nlm.nih.gov/pubmed/22718528 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201200642 |
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