Wird geladen...
Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols
We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO(2) extrusion and reduction of the in situ formed radical yields a carbanion capable of reacting with aliphatic aldehydes as electrophil...
Gespeichert in:
| Veröffentlicht in: | Chem Sci |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Royal Society of Chemistry
2019
|
| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6524566/ https://ncbi.nlm.nih.gov/pubmed/31183069 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01356c |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|