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Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols
We present a redox-neutral method for the photocatalytic generation of carbanions. Benzylic carboxylates are photooxidized by single electron transfer; immediate CO(2) extrusion and reduction of the in situ formed radical yields a carbanion capable of reacting with aliphatic aldehydes as electrophil...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6524566/ https://ncbi.nlm.nih.gov/pubmed/31183069 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01356c |
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