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Photocarboxylation of Benzylic C–H Bonds
[Image: see text] The carboxylation of sp(3)-hybridized C–H bonds with CO(2) is a challenging transformation. Herein, we report a visible-light-mediated carboxylation of benzylic C–H bonds with CO(2) into 2-arylpropionic acids under metal-free conditions. Photo-oxidized triisopropylsilanethiol was u...
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| Publicado no: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2019
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6686948/ https://ncbi.nlm.nih.gov/pubmed/31280561 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05360 |
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