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Photocarboxylation of Benzylic C–H Bonds

[Image: see text] The carboxylation of sp(3)-hybridized C–H bonds with CO(2) is a challenging transformation. Herein, we report a visible-light-mediated carboxylation of benzylic C–H bonds with CO(2) into 2-arylpropionic acids under metal-free conditions. Photo-oxidized triisopropylsilanethiol was u...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Meng, Qing-Yuan, Schirmer, Tobias E., Berger, Anna Lucia, Donabauer, Karsten, König, Burkhard
フォーマット: Artigo
言語:Inglês
出版事項: American Chemical Society 2019
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6686948/
https://ncbi.nlm.nih.gov/pubmed/31280561
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05360
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