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Photocatalytic Barbier reaction – visible-light induced allylation and benzylation of aldehydes and ketones

We report a photocatalytic version of the Barbier type reaction using readily available allyl or benzyl bromides and aromatic aldehydes or ketones as starting materials to generate allylic or benzylic alcohols. The reaction proceeds at room temperature under visible light irradiation with the organi...

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Publicado en:Chem Sci
Main Authors: Berger, Anna Lucia, Donabauer, Karsten, König, Burkhard
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2018
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6148494/
https://ncbi.nlm.nih.gov/pubmed/30288242
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02038h
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