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Beyond Benzyl Grignards: Facile Generation of Benzyl Carbanions from Styrenes

[Image: see text] The facile generation of benzyl anion equivalents from styrenes has been achieved. A Cu-catalyzed hydroboration is used in conjunction with sterically-induced cleavage of the C-B bond with tBuOK. Quenching this reactive intermediate with heterocumulene electrophiles, including CO(2...

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Vydáno v:Chemistry
Hlavní autoři: Grigg, R. David, Rigoli, Jared W., Van Hoveln, Ryan, Neale, Samuel, Schomaker, Jennifer M.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4490829/
https://ncbi.nlm.nih.gov/pubmed/22718528
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201200642
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