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A N(3)S((thioether))-Ligated Cu(II)-Superoxo with Enhanced Reactivity
Previous efforts to synthesize a cupric superoxide complex possessing a thioether donor have resulted in the formation of an end-on trans-peroxodicopper(II) species, [{(Ligand)Cu(II)}(2)(μ-1,2-O(2)(2−))](2+). Redesign/modification of previous N(3)S tetradentate ligands has now allowed for the stabil...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4482613/ https://ncbi.nlm.nih.gov/pubmed/25697226 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja511504n |
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