A N(3)S((thioether))-Ligated Cu(II)-Superoxo with Enhanced Reactivity

Previous efforts to synthesize a cupric superoxide complex possessing a thioether donor have resulted in the formation of an end-on trans-peroxodicopper(II) species, [{(Ligand)Cu(II)}(2)(μ-1,2-O(2)(2−))](2+). Redesign/modification of previous N(3)S tetradentate ligands has now allowed for the stabil...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Kim, Sunghee, Lee, Jung Yoon, Cowley, Ryan E., Ginsbach, Jake W., Siegler, Maxime A., Solomon, Edward I., Karlin, Kenneth D.
Format: Artigo
Language:Inglês
Published: 2015
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4482613/
https://ncbi.nlm.nih.gov/pubmed/25697226
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja511504n
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