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Total synthesis of (−)-kopsinine and ent-(+)-kopsinine
The total synthesis of (−)-kopsinine and its unnatural enantiomer is detailed, enlisting a late-stage SmI(2)-mediated transannular free radical conjugate addition reaction for construction of the core bicyclo[2.2.2]octane ring system with strategic C21–C2 bond formation. Key to the approach is assem...
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| 出版年: | Tetrahedron |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2014
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4461145/ https://ncbi.nlm.nih.gov/pubmed/26074629 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2014.07.094 |
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