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Total synthesis of (−)-kopsinine and ent-(+)-kopsinine

The total synthesis of (−)-kopsinine and its unnatural enantiomer is detailed, enlisting a late-stage SmI(2)-mediated transannular free radical conjugate addition reaction for construction of the core bicyclo[2.2.2]octane ring system with strategic C21–C2 bond formation. Key to the approach is assem...

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Bibliografski detalji
Izdano u:Tetrahedron
Glavni autori: Lee, Kiyoun, Boger, Dale L.
Format: Artigo
Jezik:Inglês
Izdano: 2014
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4461145/
https://ncbi.nlm.nih.gov/pubmed/26074629
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2014.07.094
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