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Chiral Amine Ee Determination Using Self-Assembled Octahedral Fe(II)-Imine Complexes
A receptor assembly composed of iron(II) triflate and pyridine-2,6-dicarbaldehyde is used to determine the enantiomeric excess of alpha-chiral primary amines using circular dichroism spectroscopy. The alpha chiral amines condense with the dialdehyde to form a diimine, which forms a 2:1 octahedral co...
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| Publicado no: | Chirality |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4394993/ https://ncbi.nlm.nih.gov/pubmed/25664936 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chir.22426 |
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