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Diazo Groups Endure Metabolism and Enable Chemoselectivity in Cellulo
[Image: see text] We introduce a stabilized diazo group as a reporter for chemical biology. ManDiaz, which is a diazo derivative of N-acetylmannosamine, is found to endure cellular metabolism and label the surface of a mammalian cell. There its diazo group can undergo a 1,3-dipolar cycloaddition wit...
Uloženo v:
| Vydáno v: | J Am Chem Soc |
|---|---|
| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
American Chemical
Society
2015
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| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4372190/ https://ncbi.nlm.nih.gov/pubmed/25658416 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5095815 |
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