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De novo asymmetric synthesis of the mezzettiaside family of natural products via the iterative use of a dual B-/Pd-catalyzed glycosylation

The first synthesis of any and all members of the mezzettiaside family of natural products has been achieved. The reported synthesis features the iterative use of the Taylor catalyst in a dual nucleophilic boron/electrophilic palladium catalyzed regioselective glycosylation. In addition, the de novo...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Bajaj, Sumit O., Sharif, Ehesan U., Akhmedov, Novruz G., O'Doherty, George A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4339001/
https://ncbi.nlm.nih.gov/pubmed/25729559
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4SC00593G
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