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De Novo Asymmetric Syntheses of SL0101 and Its Analogues via a Palladium-Catalyzed Glycosylation

[Image: see text] The enantioselective syntheses of naturally occurring kaempferol glycoside SL0101 (1a) and its analogues (1b-e), as well as their enantiomers have been achieved in 7 to 10 steps. The routes rely upon a diastereoselective palladium-catalyzed glycosylation, ketone reduction and dihyd...

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Detalhes bibliográficos
Main Authors: Shan, Mingde, O’Doherty, George A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2529254/
https://ncbi.nlm.nih.gov/pubmed/17048865
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol062076r
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