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De Novo Asymmetric Synthesis of Homo-Adenosine via a Palladium Catalyzed N-Glycosylation
[Image: see text] A highly stereoselective synthesis of L-2-deoxy-β-ribo-hexopyranosyl nucleosides from 6-chloropurine and Boc-protected pyranone has been developed. Our approach relies on the iterative application of a palladium catalyzed N-glycosylation, diastereoselective reduction and reductive...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2006
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2546502/ https://ncbi.nlm.nih.gov/pubmed/16408898 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol052664p |
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