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De Novo Formal Synthesis of (−)-Apicularen A via an Iterative Asymmetric Hydration Sequence
[Image: see text] A de novo approach to the formal total synthesis of the macrolide natural product (−)-apicularen A has been achieved in 18 steps from achiral starting materials.Both the absolute and relative stereochemistry of apicularen A were introduced by a Sharpless asymmetric dihydroxylation,...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2006
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2529256/ https://ncbi.nlm.nih.gov/pubmed/17165936 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol062595u |
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