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De Novo Synthesis of 2-Substituted Syn-1,3-Diols Via an Iterative Asymmetric Hydration Strategy
[Figure: see text] The enantioselective syntheses of several protected 4-substituted syn-3,5-dihydroxy carboxylic esters have been achieved from the corresponding achiral (E,E) or (E,Z)-1,3-dienoates. The route relies upon an enantio- and regioselective Sharpless dihydroxylation and a palladium-cata...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2006
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2515821/ https://ncbi.nlm.nih.gov/pubmed/16995681 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo061200h |
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