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De Novo Synthesis of 2-Substituted Syn-1,3-Diols Via an Iterative Asymmetric Hydration Strategy

[Figure: see text] The enantioselective syntheses of several protected 4-substituted syn-3,5-dihydroxy carboxylic esters have been achieved from the corresponding achiral (E,E) or (E,Z)-1,3-dienoates. The route relies upon an enantio- and regioselective Sharpless dihydroxylation and a palladium-cata...

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Main Authors: Ahmed, Md. Moinuddin, Mortensen, Matthew S., O'Doherty, George A.
Formato: Artigo
Idioma:Inglês
Publicado: 2006
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2515821/
https://ncbi.nlm.nih.gov/pubmed/16995681
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo061200h
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