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De Novo Asymmetric Syntheses of D- and L-Talose via an Iterative Dihydroxylation of Dienoates

[Image: see text] A short and highly efficient route to D- and L-talo-γ-lactones has been developed. The key transformation was the sequential osmium-catalyzed bis-dihydroxylation reaction of substituted 2,4-dienoates. When the first dihydroxylation reaction is performed on (2Z,4E)-dienoates using t...

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Detalhes bibliográficos
Main Authors: Ahmed, Md. Moinuddin, O’Doherty, George A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2005
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2546501/
https://ncbi.nlm.nih.gov/pubmed/16323875
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo051476+
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