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De Novo Asymmetric Syntheses of D- and L-Talose via an Iterative Dihydroxylation of Dienoates
[Image: see text] A short and highly efficient route to D- and L-talo-γ-lactones has been developed. The key transformation was the sequential osmium-catalyzed bis-dihydroxylation reaction of substituted 2,4-dienoates. When the first dihydroxylation reaction is performed on (2Z,4E)-dienoates using t...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2005
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2546501/ https://ncbi.nlm.nih.gov/pubmed/16323875 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo051476+ |
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