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Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones

An asymmetric palladium-catalyzed conjugate addition reaction of arylboronic acids to enone substrates was investigated mechanistically. Desorption electrospray ionization coupled to mass spectrometry was used to identify intermediates of the catalytic cycle and delineate differences in substrate re...

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Bibliografski detalji
Izdano u:Chem Sci
Glavni autori: Boeser, Cornelia L., Holder, Jeffrey C., Taylor, Buck L. H., Houk, K. N., Stoltz, Brian M., Zare, Richard N.
Format: Artigo
Jezik:Inglês
Izdano: The Royal Society of Chemistry 2014
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4338963/
https://ncbi.nlm.nih.gov/pubmed/25729560
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03337j
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