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Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones

An asymmetric palladium-catalyzed conjugate addition reaction of arylboronic acids to enone substrates was investigated mechanistically. Desorption electrospray ionization coupled to mass spectrometry was used to identify intermediates of the catalytic cycle and delineate differences in substrate re...

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Bibliografiska uppgifter
I publikationen:Chem Sci
Huvudupphovsmän: Boeser, Cornelia L., Holder, Jeffrey C., Taylor, Buck L. H., Houk, K. N., Stoltz, Brian M., Zare, Richard N.
Materialtyp: Artigo
Språk:Inglês
Publicerad: The Royal Society of Chemistry 2014
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4338963/
https://ncbi.nlm.nih.gov/pubmed/25729560
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03337j
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