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Carbon monoxide binding to pentacoordinate mercaptide-heme complexes: kinetic study on models for cytochrome P-450.
Mercaptide anions form exclusively penta-coordinate heme complexes [RS-heme] in polar and nonpolar solution over a wide range of mercaptide concentration. These complexes have a Soret peak at 408 nm and a formation constant of about 2.5 X 10(4) M(-1), and combine with CO to give a CO-cytochrome P-45...
Sparad:
| I publikationen: | Proc Natl Acad Sci U S A |
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| Huvudupphovsmän: | , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
National Academy of Sciences
1976
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC431108/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/1068446/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.73.10.3338 |
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