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Carbon monoxide binding to pentacoordinate mercaptide-heme complexes: kinetic study on models for cytochrome P-450.

Mercaptide anions form exclusively penta-coordinate heme complexes [RS-heme] in polar and nonpolar solution over a wide range of mercaptide concentration. These complexes have a Soret peak at 408 nm and a formation constant of about 2.5 X 10(4) M(-1), and combine with CO to give a CO-cytochrome P-45...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Chang, C K, Dolphin, D
Format: Artigo
Sprache:Inglês
Veröffentlicht: 1976
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC431108/
https://ncbi.nlm.nih.gov/pubmed/1068446
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