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Preparation and Properties of an Mn(IV–)Hydroxide Complex: Proton and Electron Transfer at a Mononuclear Manganese Site and its Relationship to the Oxygen Evolving Complex within Photosystem II
Photosynthetic water oxidation is catalyzed by a Mn(4)O(5)Ca cluster with an unprecedented arrangement of metal ions in which a single manganese center is bonded to a distorted Mn(3)O(4)Ca cubane-like structure. Several mechanistic proposals describe the unique manganese center as a site for water b...
Gorde:
| Argitaratua izan da: | Chem Sci |
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| Egile Nagusiak: | , , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2014
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4286883/ https://ncbi.nlm.nih.gov/pubmed/25580212 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C4SC00453A |
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