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Geometric and Electronic Structure of a Peroxomanganese(III) Complex Supported by a Scorpionate Ligand

A monomeric Mn(II) complex has been prepared with the facially-coordinating Tp(Ph2) ligand, (Tp(Ph2) = hydrotris(3,5-diphenylpyrazol-1-yl)borate). The X-ray crystal structure shows three coordinating solvent molecules resulting in a six-coordinate complex with Mn-ligand bond lengths that are consist...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Colmer, Hannah E., Geiger, Robert A., Leto, Domenick F., Wijeratne, Gayan B., Day, Victor W., Jackson, Timothy A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2014
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4237624/
https://ncbi.nlm.nih.gov/pubmed/25312785
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4dt02483d
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