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Mn(III)-Peroxo Adduct Supported by a New Tetradentate Ligand Shows Acid-Sensitive Aldehyde Deformylation Reactivity
The new tetradentate L(7)BQ ligand (L(7)BQ = 1,4-di(quinoline-8-yl)-1,4-diazepane) has been synthesized and shown to support Mn(II) and Mn(III)-peroxo complexes. X-ray crystallography of the [Mn(II)(L(7)BQ)(OTf)(2)] complex shows a monomeric Mn(II) center with the L(7)BQ ligand providing four donor...
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| Udgivet i: | Dalton Trans |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6176719/ https://ncbi.nlm.nih.gov/pubmed/30183042 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt02300j |
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