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Synthesis of Alkyl Halides from Aldehydes via Deformylative Halogenation
An unprecedented deformylative halogenation of aldehydes to alkyl halides is presented. Under oxidative conditions, 1,4-dihydropyridine (DHP), derived from an aldehyde, generated a C(sp3)− radical that coupled with a halogen radical that was generated from inexpensive and atom-economical halogen sou...
שמור ב:
| הוצא לאור ב: | Org Lett |
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| Main Authors: | , , , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2019
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6525078/ https://ncbi.nlm.nih.gov/pubmed/31050440 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b01337 |
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