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Reaction Landscape of a Pentadentate N5-Ligated Mn(II) Complex with O(2)(•−) and H(2)O(2) Includes Conversion of a Peroxomanganese(III) Adduct to a Bis(μ-oxo)dimanganese(III,IV) Species
Herein we describe the chemical reactivity of the mononuclear [Mn(II)(N4py)(OTf)](OTf) (1) complex with hydrogen peroxide and superoxide. Treatment of 1 with one equivalent superoxide at −40 °C in MeCN formed the peroxomanganese(III) adduct, [Mn(III)(O(2))(N4py)](+) (2) in ~30% yield. Complex 2 deca...
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| Publicado no: | Dalton Trans |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4498396/ https://ncbi.nlm.nih.gov/pubmed/23872704 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3dt51277k |
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