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Spectroscopic and Computational Investigation of Low-Spin Mn(III) Bis(scorpionate) Complexes
Six-coordinate Mn(III) complexes are typically high-spin (S = 2), however, the scorpionate ligand, both in its traditional, hydridotris(pyrazolyl)borate form, Tp(−) and Tp*(−) (the latter with 3,5-dimethylpyrazole substituents) and in an aryltris(carbene)borate (i.e., N-heterocyclic carbene, NHC) fo...
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| Publicado no: | Eur J Inorg Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5507630/ https://ncbi.nlm.nih.gov/pubmed/28713219 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201501250 |
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