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Enzymatic and Cryoreduction EPR Studies of the Hydroxylation of Methylated N(ω)-Hydroxy-l-arginine Analogues by Nitric Oxide Synthase from Geobacillus stearothermophilus
[Image: see text] Nitric oxide synthase (NOS) catalyzes the conversion of l-arginine to l-citrulline and NO in a two-step process involving the intermediate N(ω)-hydroxy-l-arginine (NHA). It was shown that Cpd I is the oxygenating species for l-arginine; the hydroperoxo ferric intermediate is the re...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4204881/ https://ncbi.nlm.nih.gov/pubmed/25251261 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi500485z |
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