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Intramolecular C(sp(3))—H amination of arylsulfonyl azides with engineered and artificial myoglobin-based catalysts

The direct conversion of aliphatic C—H bonds into C—N bonds provides an attractive approach to the introduction of nitrogen-containing functionalities in organic molecules. Following our recent discovery that cytochrome P450 enzymes can catalyze the cyclization of arylsulfonyl azide compounds via an...

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Main Authors: Bordeaux, Melanie, Singh, Ritesh, Fasan, Rudi
Formato: Artigo
Idioma:Inglês
Publicado: 2014
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4182183/
https://ncbi.nlm.nih.gov/pubmed/24890656
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmc.2014.05.015
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