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Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobin
The oxidation of primary azides to aldehydes constitutes a convenient but underdeveloped transformation for which no efficient methods are available. Here, we demonstrate that engineered variants of the hemoprotein myoglobin can catalyze this transformation with high efficiency (up to 8500 turnovers...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4754990/ https://ncbi.nlm.nih.gov/pubmed/26900445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02857d |
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