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Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobin
The oxidation of primary azides to aldehydes constitutes a convenient but underdeveloped transformation for which no efficient methods are available. Here, we demonstrate that engineered variants of the hemoprotein myoglobin can catalyze this transformation with high efficiency (up to 8500 turnovers...
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| Gepubliceerd in: | Chem Sci |
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| Hoofdauteurs: | , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
Royal Society of Chemistry
2016
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4754990/ https://ncbi.nlm.nih.gov/pubmed/26900445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02857d |
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