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Intramolecular C(sp(3))—H amination of arylsulfonyl azides with engineered and artificial myoglobin-based catalysts
The direct conversion of aliphatic C—H bonds into C—N bonds provides an attractive approach to the introduction of nitrogen-containing functionalities in organic molecules. Following our recent discovery that cytochrome P450 enzymes can catalyze the cyclization of arylsulfonyl azide compounds via an...
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| Autors principals: | , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4182183/ https://ncbi.nlm.nih.gov/pubmed/24890656 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmc.2014.05.015 |
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