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Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobin
The oxidation of primary azides to aldehydes constitutes a convenient but underdeveloped transformation for which no efficient methods are available. Here, we demonstrate that engineered variants of the hemoprotein myoglobin can catalyze this transformation with high efficiency (up to 8500 turnovers...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4754990/ https://ncbi.nlm.nih.gov/pubmed/26900445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02857d |
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