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Rates of Hexadehydro-Diels–Alder (HDDA) Cyclizations: Impact of the Linker Structure

[Image: see text] The rates of the hexadehydro-Diels–Alder (HDDA) reaction of substrates containing, minimally, a 1,3,8-triyne subunit are reported. Several series of related substrates, differing in the nature of the three-atom tether that links the 1,3-diyne and diynophile, were examined. Seemingl...

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Hlavní autoři: Woods, Brian P., Baire, Beeraiah, Hoye, Thomas R.
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2014
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4156263/
https://ncbi.nlm.nih.gov/pubmed/25153729
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol502131r
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